validamycin A

Term ID

CHEBI:29703

Synonyms

• (+)-validamycin A
• (1R,2R,3S,4S,6R)-2,3-dihydroxy-6-(hydroxymethyl)-4-{[(1S,4R,5S,6S)-4,5,6-trihydroxy-3-(hydroxymethyl)cyclohex-2-en-1-yl]amino}cyclohexyl beta-D-glucopyranoside
• (1S-(1alpha,4alpha,5beta,6alpha))-1,5,6-trideoxy-4-O-beta-D-glucopyranosyl-5-(hydroxymethyl)-1-((4,5,6-trihydroxy-3-(hydroxymethyl)-2-cyclohexen-1-yl)amino)-D-chiro-inositol
• 1,5,6-trideoxy-4-O-beta-D-glucopyranosyl-5-(hydroxymethyl)-1-[[(1S,4R,5S,6S)-4,5,6-trihydroxy-3-(hydroxymethyl)-2-cyclohexen-1-yl]amino]-D-chiro-inositol
• 1L-(1,3,4/2,6)-2,3-dihydroxy-6-hydroxymethyl-4-((1S,4R,5S,6S)-4,5,6-trihydroxy-3-hydroxymethylcyclohex-2-enylamino)cyclohexyl beta-D-glucopyranoside
• D-1,5,6-trideoxy-3-O-beta-D-glucopyranosyl-5-(hydroxymethyl)-1-((4,5,6-trihydroxy-3-(hydroxymethyl)-2-cyclohexen-1-yl)amino)-D-chiroinositol
• jinganmycin A
• T-7545-A
• Validacin
• Validamycin
• Valimon

Definition

A member of the class of validamycins that is (1R,2S,3S,4S,6R)-4-amino-6-(hydroxymethyl)cyclohexane-1,2,3-triol in which the hydroxy group at position 1 has been converted to its beta-D-glucoside and in which one of the hydrogens attached to the nitrogen is replaced by a (1R,4R,5R,6S)-4,5,6-trihydroxy-3-(hydroxymethyl)cyclohex-2-en-1-yl group. It is the major validamycin produced by Streptomyces hygroscopicus.

References

• BPDB:677
• CAS:37248-47-8
• HMDB:HMDB0036592
• KEGG:C12112
• KNApSAcK:C00018797
• MetaCyc:VALIDAMYCIN-A
• PMID:18943474
• PMID:20952185
• PMID:22036231
• PMID:22481376
• PMID:22521597
• PMID:23295203
• PMID:23340099
• PMID:25060680
• PMID:25102722
• PMID:25236210
• PMID:3269390
• PMID:3570986
• PMID:5549382
• PMID:6548220
• PMID:9242988
• PMID:9813313
• Pesticides:validamycin
• Reaxys:5319831
• Wikipedia:Validamycin

Ontology

ChEBI  ( EBI )

Resources

CTD