grasshopper ketone

Term ID

CHEBI:177873

Synonyms

• (-)-grasshopper ketone
• (3M)-4-[(2R,4S)-2,4-dihydroxy-2,6,6-trimethylcyclohexylidene]but-3-en-2-one
• (3Ra)-4-[(2R,4S)-2,4-dihydroxy-2,6,6-trimethylcyclohexylidene]but-3-en-2-one

Definition

A member of the class of allenes that is cyclohexane substituted by 3-oxobut-1-en-1-ylidene, methyl, hydroxy, hydroxy, methyl and methyl groups at positions 1, 2, 2, 4, 6 and 6, respectively (the 2R,3R,4S-stereoisomer). It is isolated from the grasshopper, Romalea microptera.

References

• agr:IND20419195
• agr:IND20511662
• cas:41703-38-2
• chemspider:10200510
• foodb.food:FDB013523
• knapsack:C00031831
• metacyc.compound:CPD-7201
• pubmed:12926890
• pubmed:15132542
• pubmed:22364828
• pubmed:22530677
• pubmed:24761641
• pubmed:24946547
• pubmed:27608302
• pubmed:29090551
• pubmed:29600618
• pubmed:30132649
• pubmed:30982318

Ontology

ChEBI  ( EBI )