bassianolide

Term ID

CHEBI:145108

Synonyms

• (-)-bassianolide
• (3S,6R,9S,12R,15S,18R,21S,24R)-3,9,15,21-tetraisobutyl-6,12,18,24-tetraisopropyl-4,10,16,22-tetramethyl-1,7,13,19-tetraoxa-4,10,16,22-tetraazacyclotetracosane-2,5,8,11,14,17,20,23-octone
• BASS
• bassianolide

Definition

A cyclodepsipeptide consisting of a cyclic tetramer of the depsipeptide D-Hiv-N-methyl-L-leucine (where D-Hiv = D-α-hydroxyisovaleric acid). Found in the fungal species Beauveria bassiana and Verticillium lecanii, it has insecticidal properties and is used as a commercial biopesticide to control of insects of agricultural, veterinary and medical significance. For elucidation of the structure, see Suzuki et al., Tetrahedron Lett. 1977 v25, 2167-2170.

References

• agr:IND79047232
• cas:64763-82-2
• pubmed:18375793
• pubmed:19285149
• pubmed:23608474
• pubmed:27676608
• pubmed:29163920
• pubmed:29507740
• pubmed:29551387
• pubmed:29909016
• pubmed:30029532
• pubmed:31388353
• pubmed:33058930
• pubmed:36984865
• pubmed:37252886
• pubmed:6620728
• pubmed:6953262

Ontology

ChEBI  ( EBI )

Resources

CTD